First, two protons combine to form a nucleus of the heavy isotope of hydrogen known as deuterium. The deuterium nucleus then combines with another proton to form the light helium isotope known as helium-3. Finally two helium-3 nuclei combine to form helium-4, releasing two protons in the process. Overall, four protons are converted into one. Protium and Deuterium are classified under the stable isotopes of hydrogen. Tritium is a stable radioactive isotope or ‘radioisotope’ of hydrogen, and it has a half-life of about 12.3 years. Among the other heavier isotopes of hydrogen, 5H is the most stable, and 7H is the minimum stable. Isotope abundances of hydrogen. In the above, the most intense ion is set to 100% since this corresponds best to the output from a mass spectrometer. This is not to be confused with the relative percentage isotope abundances which totals 100% for all the naturally occurring isotopes.
A family of people often consists of related but not identical individuals. Elements have families as well, known as isotopes. Isotopes are members of a family of an element that all have the same number of protons but different numbers of neutrons.
The number of protons in a nucleus determines the element’s atomic number on the Periodic Table. For example, carbon has six protons and is atomic number 6. Carbon occurs naturally in three isotopes: carbon 12, which has 6 neutrons (plus 6 protons equals 12), carbon 13, which has 7 neutrons, and carbon 14, which has 8 neutrons. Every element has its own number of isotopes.
The addition of even one neutron can dramatically change an isotope’s properties. Carbon-12 is stable, meaning it never undergoes radioactive decay. Carbon-14 is unstable and undergoes radioactive decay with a half-life of about 5,730 years (meaning that half of the material will be gone after 5,730 years). This decay means the amount of carbon-14 in an object serves as a clock, showing the object’s age in a process called “carbon dating.”
Isotopes have unique properties, and these properties make them useful in diagnostics and treatment applications. They are important in nuclear medicine, oil and gas exploration, basic research, and national security.
DOE Office of Science & Isotopes
Isotopes are needed for research, commerce, medical diagnostics and treatment, and national security. However, isotopes are not always available in sufficient quantities or at reasonable prices. The DOE Isotope Program addresses this need. The program produces and distributes radioactive and stable isotopes that are in short supply, including byproducts, surplus materials, and related isotope services. The program also maintains the infrastructure required to produce and supply priority isotope products and related services. Finally, it conducts research and development on new and improved isotope production and processing techniques.
Isotope Facts
- All elements have isotopes.
- There are two main types of isotopes: stable and unstable (radioactive).
- There are 254 known stable isotopes.
- All artificial (lab-made) isotopes are unstable and therefore radioactive; scientists call them radioisotopes.
- Some elements can only exist in an unstable form (for example, uranium).
- Hydrogen is the only element whose isotopes have unique names: deuterium for hydrogen with one neutron and tritium for hydrogen with two neutrons.
Resources and Related Terms
- National Isotope Development Center (Isotope Basics)
Scientific terms can be confusing. DOE Explains offers straightforward explanations of key words and concepts in fundamental science. It also describes how these concepts apply to the work that the Department of Energy’s Office of Science conducts as it helps the United States excel in research across the scientific spectrum.
Learning Objective
- Discuss the chemical properties of hydrogen’s naturally occurring isotopes.
Key Points
- Protium is the most prevalent hydrogen isotope, with an abundance of 99.98%. It consists of one proton and one electron. It is typically not found in its monoatomic form, but bonded with itself (H2) or other elements.
- Deuterium is a hydrogen isotope consisting of one proton, one neutron and one electron. It has major applications in nuclear magnetic resonance studies.
- Tritium is a hydrogen isotope consisting of one proton, two neutrons and one electron. It is radioactive, with a half-life of 12.32 years.
Terms
- diatomicConsisting of two atoms.
- isotopeForms of an element where the atoms have a different number of neutrons within their nuclei. As a consequence, atoms of the same isotope will have the same atomic number, but a different mass number.
Properties of Isotopes of Hydrogen
Hydrogen has three naturally occurring isotopes: 1H (protium), 2H (deuterium), and 3H (tritium). Other highly unstable nuclei (4H to 7H) have been synthesized in the laboratory, but do not occur in nature. The most stable radioisotope of hydrogen is tritium, with a half-life of 12.32 years. All heavier isotopes are synthetic and have a half-life less than a zeptosecond (10-21 sec). Of these, 5H is the most stable, and the least stable isotope is 7H .
Protium
1H is the most common hydrogen isotope with an abundance of more than 99.98%. The nucleus of this isotope consists of only a single proton (atomic number = mass number = 1) and its mass is 1.007825 amu. Hydrogen is generally found as diatomic hydrogen gas H2, or it combines with other atoms in compounds—monoatomic hydrogen is rare. The H–H bond is one of the strongest bonds in nature, with a bond dissociation enthalpy of 435.88 kJ/mol at 298 K. As a consequence, H2 dissociates to only a minor extent until higher temperatures are reached. At 3000K, the degree of dissociation is only 7.85%. Hydrogen atoms are so reactive that they combine with almost all elements.
Deuterium
2H, or deuterium (D), is the other stable isotope of hydrogen. It has a natural abundance of ~156.25 ppm in the oceans, and accounts for approximately 0.0156% of all hydrogen found on earth. The nucleus of deuterium, called a deuteron, contains one proton and one neutron (mass number = 2), whereas the far more common hydrogen isotope, protium, has no neutrons in the nucleus. Because of the extra neutron present in the nucleus, deuterium is roughly twice the mass of protium (deuterium has a mass of 2.014102 amu, compared to the mean hydrogen atomic mass of 1.007947 amu). Deuterium occurs in trace amounts naturally as deuterium gas, written 2H2 or D2, but is most commonly found in the universe bonded with a protium 1H atom, forming a gas called hydrogen deuteride (HD or 1H2H).
Chemically, deuterium behaves similarly to ordinary hydrogen (protium), but there are differences in bond energy and length for compounds of heavy hydrogen isotopes, which are larger than the isotopic differences in any other element. Bonds involving deuterium and tritium are somewhat stronger than the corresponding bonds in protium, and these differences are enough to make significant changes in biological reactions. Deuterium can replace the normal hydrogen in water molecules to form heavy water (D2O), which is about 10.6% denser than normal water. Heavy water is slightly toxic in eukaryotic animals, with 25% substitution of the body water causing cell division problems and sterility, and 50% substitution causing death by cytotoxic syndrome (bone marrow failure and gastrointestinal lining failure). Consumption of heavy water does not pose a health threat to humans. It is estimated that a 70 kg person might drink 4.8 liters of heavy water without serious consequences.
The most common use for deuterium is in nuclear resonance spectroscopy. As nuclear magnetic resonance (NMR) requires compounds of interest to be dissolved in solution, the solution signal should not register in the analysis. As NMR analyzes the nuclear spins of hydrogen atoms, the different nuclear spin property of deuterium is not ‘seen’ by the NMR instrument, making deuterated solvents highly desirable due to the lack of solvent-signal interference.
Tritium
3H is known as tritium and contains one proton and two neutrons in its nucleus (mass number = 3). It is radioactive, decaying into helium-3 through beta-decay accompanied by a release of 18.6 keV of energy. It has a half-life of 12.32 years. Naturally occurring tritium is extremely rare on Earth, where trace amounts are formed by the interaction of the atmosphere with cosmic rays.
Heavier Synthetic Isotopes
4H contains one proton and three neutrons in its nucleus. It is a highly unstable isotope of hydrogen. It has been synthesized in the laboratory by bombarding tritium with fast-moving deuterium nuclei. In this experiment, the tritium nuclei captured neutrons from the fast-moving deuterium nucleus. The presence of the hydrogen-4 was deduced by detecting the emitted protons. Its atomic mass is 4.02781 ± 0.00011 amu. It decays through neutron emission with a half-life of 1.39 ×10−22 seconds.
5H is another highly unstable heavy isotope of hydrogen. The nucleus consists of a proton and four neutrons. It has been synthesized in a laboratory by bombarding tritium with fast-moving tritium nuclei. One tritium nucleus captures two neutrons from the other, becoming a nucleus with one proton and four neutrons. The remaining proton may be detected and the existence of hydrogen-5 deduced. It decays through double neutron emission and has a half-life of at least 9.1 × 10−22 seconds.
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6H decays through triple neutron emission and has a half-life of 2.90×10−22 seconds. Best th8 layout. It consists of one proton and five neutrons.
7H consists of one proton and six neutrons. It was first synthesized in 2003 by a group of Russian, Japanese and French scientists at RIKEN’s RI Beam Science Laboratory, by bombarding hydrogen with helium-8 atoms. The helium-8’s neutrons were donated to the hydrogen’s nucleus. The two remaining protons were detected by the “RIKEN telescope”, a device composed of several layers of sensors, positioned behind the target of the RI Beam cyclotron.
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